126045-48-5Relevant academic research and scientific papers
Polyfuryl(aryl)alkanes and their derivatives 16. Convenient path to benzofuran ketones
Abaev,Gutnov,Butin
, p. 529 - 532 (1998)
2-(3-Oxobutyl)-3-(5-methyl-2-furyl)benzofurans were synthesized by the recyclization of 2-hydroxyarylbis(5-methyl-2-furyl)methanes in methanol saturated with hydrogen chloride. They can also be obtained by the reaction of salicylaldehydes and sylvane in a
Polyfuryl(aryl)alkanes and their derivatives. 10. Selective synthesis of 2-hydroxy-aryldifurylmethanes
Gutnov,Abaev,Butin,Zavodnik,Kul'nevich
, p. 141 - 145 (2007/10/03)
It was shown that Me3SiCl, B(OH)3, PhB(OH)2, and B2O3 can act as catalysts for the selective synthesis of 2-hydroxyaryldifurylmethanes. It was established by x-ray crystallographic analysis that the m
Polyfuryl(Aryl)Alkanes And Their Derivatives. 7. New Recyclization And Cyclization Reactions In The 2-Hydroxyaryldifurylmethane Series
Butin, A. V.,Krapivin, G. D.,Zavodnik, V. E.,Kul'nevich, V. G.
, p. 524 - 533 (2007/10/02)
Reaction of 2-hydroxybenzaldehydes with α-methylfuran (sylvan) under acid-catalysis conditions was investigated It is shown that the reaction does not stop at the step involving formation of 2-hydroxyarylfuryl-methanes but proceeeds further with opening of one of the furan rings and recyclization to 3-furylbenzo-furan derivatives.The latter in turn undergo transformations that lead to new heterocyclic systems - 5,6-dihydro-2,4-dimethyl-4-(5-methyl-2-furyl)-4H-benzofurocyclopentafurans.Data from the IR, PMR, and mass spectra, alternative synthesis, and x-ray diffraction analysis were used to confirm structures of the synthesized compounds.
NEW SYNTHESIS OF SUBSTITUTED DIFURYL OR DITHIENYL METHANES
Riad, A.,Mouloungui, Z.,Delmas, M.,Gaset, A.
, p. 3169 - 3174 (2007/10/02)
New trisubstituted methanes derivatives are quantitatively and selectively obtained by condensation of 2-methylfuran or 2-methylthiophene with diverse aldehydes using macroporous ion-exchange resin as catalyst.Hydration rate of organic phase and sulfonic sites of catalyst determines a proper reaction progress.
