126045-70-3Relevant academic research and scientific papers
SYNTHESIS OF FLUORINATED DERIVATIVES OF METHIONINE AND 5'-DEOXY-5'-(METHYLTHIO)-ADENOSINE USING THE McCARTHY TRANSFORMATION OF SULFOXIDES TO α-FLUORO THIOETHERS
Sufrin, Janice R.,Spiess, Arthur J.,Alks, Vitauts
, p. 177 - 182 (1990)
Treatment of N-acetylmethionine sulfoxide methyl ester with diethylaminosulfur trifluoride (DAST) or dimethylaminosulfur trifluoride (meDAST) yielded N-acetyl-S-(monofluoromethyl)homocysteine methyl ester as the sole fluorinated product.In contrast, treatment of 2',3'-di-O-acetyl-5'-(methylthio)adenosine sulfoxide with DAST or meDAST unexpectedly produced three novel fluorinated products.
