126065-13-2Relevant academic research and scientific papers
Photochemistry of Aminoketones, XII. The Behaviour of N-Acylglycinate Rotamers in the Photochemical Glycine->Proline Conversion
Kernchen, Frank,Henning, Hans-Georg
, p. 253 - 268 (2007/10/02)
The rate of the diastereoselective generation of methyl 3r,2t-N-acyl-3-hydroxy-3-phenyl-prolinates 5 from n,?*-excited methyl N-acyl-N-(β-benzoylethyl)-glycinates 4 depends on the height of the barrier ΔGc(excit.) of amide rotation i
