1260760-80-2Relevant articles and documents
Gold-catalyzed rearrangement of substituted allyl aryl ethers
Vyvyan, James R.,Dimmitt, Heidi E.,Griffith, Jennifer K.,Steffens, Laura D.,Swanson, Rebecca A.
experimental part, p. 6666 - 6669 (2011/02/21)
Triphenylphosphinegold(I) complexes catalyze the Claisen-type rearrangement of aryl allyl ethers to the corresponding branched and linear products. The product distribution depends on the olefin geometry of the allylic ether. Stereochemical transfer experiments support an ionic mechanism.