126079-38-7

Basic information

• Product Name: 1,2-Bis<2-(bromomethyl)benzyl>benzene
• Synonyms: 1,2-Bis<2-(bromomethyl)benzyl>benzene
• CAS NO: 126079-38-7
• Molecular Weight: 444.209
• Mol File: 126079-38-7.mol

Chemical Properties

• CAS DataBase Reference: 1,2-Bis<2-(bromomethyl)benzyl>benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-Bis<2-(bromomethyl)benzyl>benzene(126079-38-7)
• EPA Substance Registry System: 1,2-Bis<2-(bromomethyl)benzyl>benzene(126079-38-7)

Safety Data

• Hazardous Substances Data: 126079-38-7(Hazardous Substances Data)

Upstream product

• 17100-66-2 2-(tetrahydropyranyloxy)methylbromobenzene 
• 91-13-4 α,α'-dibromo-o-xylene 
• 1026866-07-8 C₃₂H₃₈O₄ 
• 52711-30-5 1-bromo-2-(methoxymethyl)benzene 
• 95-46-5 2-methylphenyl bromide 
• 349453-00-5 1,2-bis(2-methoxymethylbenzyl)benzene 
• 126079-36-5 1,2-Bis<2-(hydroxymethyl)benzyl>benzene 

Downstream Products

• 154618-92-5 1,2-Bis<2-<2-(2-formylbenzyl)benzyl>benzyl>benzene 
• 154618-87-8 1,2-Bis<2-(2-formylbenzyl)benzyl>benzene 
• 1027527-66-7 C₆₀H₆₂O₄ 
• 148319-96-4 1,2-Bis<2-<2-<2-(hydroxymethyl)benzyl>benzyl>benzyl>benzene 
• 148319-95-3 1,2-Bis<2-<2-(bromomethyl)benzyl>benzyl>benzene 
• 148319-94-2 1,2-Bis<2-<2-(hydroxymethyl)benzyl>benzyl>benzene 

Relevant articles and documents

Medium-sized cyclophanes. Part 55. Synthesis and conformational studies of [2.1.1] orthocyclophanes

[2.1.1]Orthocyclophanes 2 are prepared by pyrolysis of the corresponding 2-thia[3.1.1]orthocyclophane 2,2-dioxides 9, which are prepared by the reaction of 1,2-bis(2-bromomethylbenzyl)benzenes 7 with Na2S in ethanol under high dilution conditions, followed by oxidation with m-chloroperbenzoic acid. The conformational studies on [2.1.1]orthocyclophanes 2, which adopt flexible saddle and crown structures in comparison with the corresponding 10,15-dihydro-5H-tribenzo[a,d,g]cyclononene ([1.1.1]orthocyclophane) 1, are discussed.

Biscyclophanes. Part 2: Regioselectivity in the Acid-catalysed Cycloalkylation of Benzylbenzylic Alcohol (BBA)

o-Benzylbenzylic alcohols (o-BBAs), in which the terminnal benzyl alcohol is substituted by repeating benzyl chains all in the ortho sense, have been found to have conspicuous regioselectivity in acid-catalysed cycloalkylation, giving rise to various cycl