126086-72-4

Basic information

• Product Name: N-Isopropyl-3-broMoaniline
• Synonyms: N-Isopropyl-3-broMoaniline
• CAS NO: 126086-72-4
• Molecular Formula: C9H12BrN
• Molecular Weight: 214.10228
• Mol File: 126086-72-4.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N-Isopropyl-3-broMoaniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-Isopropyl-3-broMoaniline(126086-72-4)
• EPA Substance Registry System: N-Isopropyl-3-broMoaniline(126086-72-4)

Safety Data

• Hazardous Substances Data: 126086-72-4(Hazardous Substances Data)

Upstream product

• 591-19-5 m-Bromoaniline 
• 108-36-1 1,3-dibromobenzene 
• 75-31-0 isopropylamine 

Relevant articles and documents

Palladium-catalyzed monoamination of dihalogenated benzenes

The palladium-catalyzed monoamination of symmetric dibromobenzenes can be performed using a catalyst based on Pd2dba3 and BINAP in the presence of NaO(t-Bu). The analogous transformation of non-symmetric bromoiodobenzenes is most effectively performed with Xantphos as the ligand, while reactions with BINAP were non-selective. These transformations can be scaled uneventfully to >10 g quantities. They do not require drybox or Schlenk techniques, and all reagents are weighed out in air. The resulting monobromoanilines are versatile intermediates for further synthetic transformations.