1261083-01-5Relevant academic research and scientific papers
Silylene-mediated polarity reversal of dienoates: Additions of dienoates to aldehydes at the δ-position to form trans-dioxasilacyclononenes
Ventocilla, Christian C.,Woerpel
, p. 406 - 408 (2011/04/16)
Silylene transfer to αβ,γ,δ-unsaturated carbonyl compounds produced oxasilacyclopentenes that underwent thermal additions to aldehydes to produce trans-dioxasilacyclononenes as single stereoisomers. This reaction, which converts the δ-position of the unsa
