1261085-99-7Relevant academic research and scientific papers
Nhc-catalyzed michael addition to α,β-unsaturated aldehydes by redox activation
De Sarkar, Suman,Studer, Armido
supporting information; experimental part, p. 9266 - 9269 (2011/02/25)
Through oxidative carbene catalysis the reactivity of enals can be reversed at the β position from the typical electrophilic to nucleophilic (homoenolate chemistry) further to electrophilic reactivity by two consecutive umpolung processes. These redox-act
