1261246-04-1Relevant articles and documents
Acceleration effects of phosphine ligands on the rhodium-catalyzed dehydrogenative silylation and germylation of unactivated C(sp3)-H bonds
Murai, Masahito,Takeshima, Hirotaka,Morita, Haruka,Kuninobu, Yoichiro,Takai, Kazuhiko
, p. 5407 - 5414 (2015)
The current work describes the marked rate of acceleration caused by phosphine ligands on the rhodium-catalyzed dehydrogenative silylation and germylation of unactivated C(sp3)-H bonds. The reactivity was affected by the steric and electronic n
Rhodium-catalyzed intramolecular silylation of unactivated C(sp 3)-H bonds
Kuninobu, Yoichiro,Nakahara, Takahiro,Takeshima, Hirotaka,Takai, Kazuhiko
supporting information, p. 426 - 428 (2013/03/13)
The treatment of a variety of hydrosilanes, each incorporating a benzylic C(sp3)-H bond, with a rhodium catalyst resulted in intramolecular dehydrogenative silylation. This silylation reaction was found to occur at typically unreactive C(sp3)-H bonds located at terminal positions on alkyl chains. Interestingly, the rhodium catalyst also promoted regioselective silylation at a site internal to an alkyl chain.