126134-79-0Relevant academic research and scientific papers
Stereoselective Formation of trans-1,2-Disubstituted Cyclopentanes by Intramolecular Cyclisation of Allylsilane Alkylidene 1,3-Dioxo Compounds
Tietze, Lutz F.,Ruther, Michael
, p. 1387 - 1395 (2007/10/02)
The alkylidene 1,3-dioxo compounds 4a-d with an allylsilane moiety undergo a fluoride-, Lewis acid- and TMSOTf-induced intramolecular cyclisation to give almost exclusively the trans-1,2-disubstituted cyclopentanes 5a-d in good to excellent yields.The dia
