126144-27-2Relevant academic research and scientific papers
THE REACTION OF α,α-DICHLOROBENZYLTRIMETHYLSILANE WITH ALDEHYDES AND KETONES.
Larson, Gerald L.,Prieto, Jose A.,Valle, Luis del
, p. 1405 - 1412 (2007/10/02)
The reaction of α,α-dichlorobenzyltrimethylsilane with carbonyl compounds in the presence of fluoride ion fails to give reasonable yields of the α,α-dichlorobenzyl adducts except when carried out in the presence of zinc iodide and in HMPA as solvent.Under these conditions moderate yields of the adducts can be obtained with cyclohexanone, cyclohexenone, benzaldehyde and trans cinnamaldehyde.These reactions were compared with those of α,α-dichlorobenzyllithium.
