1261475-45-9

Basic information

• Product Name: (3-Bromo-2-nitrophenyl)methanol
• Synonyms: (3-Bromo-2-nitrophenyl)methanol
• CAS NO: 1261475-45-9
• Molecular Formula: C₇H₆BrNO₃
• Molecular Weight: 232.03144
• Mol File: 1261475-45-9.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 312.0±27.0 °C(Predicted)
• Appearance: /
• Density: 1.767±0.06 g/cm3(Predicted)
• Storage Temp.: 2-8°C
• PKA: 13.69±0.10(Predicted)
• CAS DataBase Reference: (3-Bromo-2-nitrophenyl)methanol(CAS DataBase Reference)
• NIST Chemistry Reference: (3-Bromo-2-nitrophenyl)methanol(1261475-45-9)
• EPA Substance Registry System: (3-Bromo-2-nitrophenyl)methanol(1261475-45-9)

Safety Data

• Hazardous Substances Data: 1261475-45-9(Hazardous Substances Data)

Usage

General Description

(3-Bromo-2-nitrophenyl)methanol is a chemical compound with the molecular formula C7H6BrNO4. It is a pale yellow solid with a molecular weight of 228.03 g/mol. (3-Bromo-2-nitrophenyl)methanol is commonly used as a building block in the synthesis of various pharmaceuticals and agrochemicals due to its ability to undergo various chemical reactions, such as nucleophilic substitution and reduction. It is also known for its potential use as a starting material for the preparation of various functionalized compounds with potential biological activities. Additionally, (3-Bromo-2-nitrophenyl)methanol may be used in the field of organic chemistry for the study and development of new synthetic methodologies.

Upstream product

• 585-76-2 m-bromobenzoic acid 
• 552-89-6 2-nitro-benzaldehyde 
• 882772-99-8 3-bromo-2-nitrobenzaldehyde 
• 13402-32-9 1,3-dibromo-2-nitrobenzene 
• 400629-31-4 2-(3-bromo-2-nitrophenyl)acetic acid 
• 116529-61-4 3-bromo-2-nitrobenzoic acid 

Downstream Products

• 882772-99-8 3-bromo-2-nitrobenzaldehyde 

Relevant articles and documents

A 3 - bromo -2 - nitrobenzaldehyde chemical synthesis method

The invention relates to a chemical synthesis method of 3-bromo-2-nitrobenzaldehyde. The chemical synthesis method is characterized by using 1,3-dibromo-2-nitrobenzene as a raw material and carrying out five-step reactions including substitution, decarboxylation, oxidation, reduction and hydroformylation, and comprises the following steps of adding 1,3-dibromo-2-nitrobenzene, dimethyl malonate and alkali to an organic solvent to react to prepare 2-(3-bromo-2-nitrobenzaldehyde)-dimethyl malonate; dissolving 2-(3-bromo-2-nitrobenzaldehyde)-dimethyl malonate obtained in the former step in a tetrahydrofuran or acetone solvent, and adding a hydrochloric acid solution to react to prepare 2-(3-bromo-2-nitrobenzaldehyde)-acetic acid; adding a sodium hydroxide water solution and potassium permanganate to react to obtain 3-bromo-2-nitrobenzoic acid; dissolving 3-bromo-2-nitrobenzoic acid in the tetrahydrofuran solvent, and adding borane tetrahydrofuran to react to obtain 3-bromo-2-nitrobenzyl alcohol; adding 3-bromo-2-nitrobenzyl alcohol to a dichloromethane or 1,2-dichloroethane solvent and adding manganese dioxide to react to prepare 3-bromo-2-nitrobenzaldehyde. The synthetic route has the advantages of low cost and high yield.

Tunable emissive thin films through ICT photodisruption of nitro-substituted triarylamines

UV-assisted photocleavage in the solid state of orange emitting nitro-substituted triarylamines leads to the appearance of blue emission following photodisruption of the ICT state.