126159-11-3Relevant academic research and scientific papers
General Method for the Synthesis of 1,4-Disubstituted 5-Halo-1,2,3-triazoles
Gribanov, Pavel S.,Topchiy, Maxim A.,Karsakova, Iuliia V.,Chesnokov, Gleb A.,Smirnov, Alexander Yu.,Minaeva, Lidiya I.,Asachenko, Andrey F.,Nechaev, Mikhail S.
, p. 5225 - 5230 (2017/09/29)
A general method for the synthesis of 1,4-disubstituted 5-halo-1,2,3-triazoles has been developed. The one-pot two-step process consists of a CuAAC reaction of a copper(I) acetylide with an organic azide catalyzed by (aNHC)CuCl, followed by halogenation with N-chlorosuccinimide, N-bromosuccinimide, or I2.
A general method of Suzuki-Miyaura cross-coupling of 4- and 5-halo-1,2,3-triazoles in water
Gribanov, Pavel S.,Chesnokov, Gleb A.,Topchiy, Maxim A.,Asachenko, Andrey F.,Nechaev, Mikhail S.
supporting information, p. 9575 - 9578 (2017/11/30)
A general method of the synthesis of 1,4,5-trisubstituted-1,2,3-triazoles by Suzuki-Miyaura cross-coupling from 4- and 5-halo-1,2,3-triazoles is reported. The reaction is mediated by an expanded-ring N-heterocyclic carbene palladium complex in water. The
The Chemistry of 3-(α-Cyanobenzylidene)-1-phenyltriazenes and Their Conversion to Diarylmaleimides and Phenanthrene-9,10-dicarboximides
Smith, Peter A. S.,Friar, James Jeffrey,Resemann, Wolfgang,Watson, Andrew C.
, p. 3351 - 3362 (2007/10/02)
3-(α-Cyanobenzylidene)-1-phenyltriazine (3a), the product of thermolysis of 5-azido-1,4-diphenyl-1,2,3-triazole (2), is attacked by nucleophilic reagents at the azomethine carbon.Alcohols and phenol give rise to acetals of the N-phenylamidine of phenylgly
SYNTHESIS OF 1-AMINO-5(SUBSTITUTED)AMINO-1,2,3-TRIAZOLES
L'abbe, Gerrit,Bruynseels, Maria,Beenaerts, Linda,Vandendriessche, Anna,Delbeke, Pieter,Toppet, Suzanne
, p. 343 - 348 (2007/10/02)
1-Amino-5-(substituted)amino-1,2,3-triazoles (3) are directly produced by heating 1-aryl-5-chloro-1,2,3-triazoles (1) with hydrazine.The 5-hydrazinotriazoles 2 are presumably formed first, but rearrange spontaneously under the reaction conditions.The stru
