126181-87-1Relevant articles and documents
Photochemical carbon-silicon bond forming reaction on electron-deficient alkenes by disilanes and polysilanes via photoinduced electron transfer
Mizuno, Kazuhiko,Nakanishi, Kazuhisa,Chosa, Jun-ichi,Otsuji, Yoshio
, p. 35 - 44 (2007/10/02)
The phenanthrene-sensitized photoreaction of electron-deficient alkenes with disilanes in acetonitrile gave silylated alkanes in high yields.The photosilylation occurred in a highly regioselective manner at the position β to the electron-withdrawing group