126186-75-2Relevant academic research and scientific papers
Palladium-Catalyzed Carbonyl Allylation of Diketo Compounds by Allylic Alcohols with SnCl2
Masuyama, Yoshiro,Tsunoda, Tomoyoshi,Kurusu, Yasuhiko
, p. 1647 - 1650 (2007/10/02)
Palladium-catalyzed diallylation of 1,2-diketones and 1,2-ketoaldehyde by allylic alcohol with SnCl2 in DMI was accelerated and proceeded diastereoselectively thanks to a chelation of a carbonyl group to Sn(IV) (tin alkoxide) in the corresponding monoallylated intermediates.
