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126210-91-1

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126210-91-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 126210-91-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,6,2,1 and 0 respectively; the second part has 2 digits, 9 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 126210-91:
(8*1)+(7*2)+(6*6)+(5*2)+(4*1)+(3*0)+(2*9)+(1*1)=91
91 % 10 = 1
So 126210-91-1 is a valid CAS Registry Number.

126210-91-1Downstream Products

126210-91-1Relevant articles and documents

Reaction of Aminopropanedinitrile 4-Methylbenzenesulfonate with Aromatic Aldehydes

Freeman, Fillmore,Kim, Darrick S. H. L.

, p. 657 - 663 (2007/10/02)

Aminpropanedinitril 4-methylbenzenesulfonate (ammoniopropanedinitrile p-toluenesulfonate, aminomalonitrile p-toluenesulfonate (tosylate), 1) reacts with aromatic aldehydes in methanolic sodium ethanoate to give diastereoselctively (E,E)-4-amino-1-aryl-3-cyano-4-methoxy-2-aza-1,3-butadienes (3) and trans-3,6-diaryl-2,2,5,5-tetracyanopiperazines (4).The product distribution (3:4) depends on the ratio of reactants and the structures of the substrates.Electron-releasing groups on the 4-position of the phenyl ring favor piperazine (4) formation (method B).The formation of piperazine (4) may involve synthetically useful N-protonated aryl- and cyano-stabilized azomethine ylide tautomerism of prior formed 1-aryl-3,3-dicyano-2-aza-1-propenes. 1,3-Dipolar cycloaddition reactions of the highly reactive azomethine ylides with dimethyl 1,2-ethynedicarboxylate (DMAD) give 3,4-dicarbomethoxy-2-cyano-5-aryl-3-pyrrolines, which undergo facile dehydrocyanation to 3,4-dicarbomethoxy-2-cyano-5-arylpyrroles.The possible intermediacy of ketenimines and of aryl- and cyano-stabilized 2-azaallyl anionic intermediates in equilibrium with azomethine ylides is also considered.

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