1262283-52-2Relevant articles and documents
Regioselective inversion of the hydroxyl group in d-ribo-phytosphingosine via a cyclic sulfate and bis-sulfonate intermediate
Lee, Yun Mi,Baek, Dong Jae,Lee, Seokwoo,Kim, Deukjoon,Kim, Sanghee
, p. 408 - 416 (2011/03/20)
The selective synthesis of d-xylo-and d-lyxo-phytosphingosines from commercially available d-ribo-phytosphingosine is described. Thermolysis of the N-carbonyl protected cyclic sulfate led to an inversion of configuration of the proximal hydroxyl group to