126256-45-9

Upstream product

• 126256-41-5 bis<(2,4,6-tri-tert-butylphenyl)amino>phenylchlorosilane 
• 4074-25-3 2,4,6-tri-tert-butylnitrobenzene 
• 109-72-8 n-butyllithium 
• 126256-46-0 C₄₂H₆₃N₂Si^(1-)*C₄H₁₀O*Li⁽¹⁺⁾ 
• 126256-42-6 lithium N,N'-bis(2,4,6-tri-tert-butylphenyl)phenylsilaamidide 
• 961-38-6 2,4,6-Tri-tert-butylaniline 

Relevant academic research and scientific papers

Silaamidide salts: Synthesis, structure, and reactions

Five silaamidides have been prepared and characterized: lithium N,N'-bis(2,4,6-tri-tert-butylphenyl)phenylsilaamidide (2), lithium N,N'-bis(2,4,6-tri-tert-butylphenyl)chlorosilaamidide (5), lithium N,N'-bis(2,4,6-tri-tert-butylphenyl)-n-butylsilaamidide (6), lithium N,N'-bis(2,4,6-tri-tert-butylphenyl)-tert-butylsilaamidide (7), and potassium N,N'-bis(2,4,6-tri-tert-butylphenyl)chlorosilaamidide (8). Reactions of silaamidides with alcohols, amines, hydrogen bromide, n-butyllithium, and benzaldehyde are described. The structure of 7·(12-crown-4)(THF) was determined by X-ray analysis: crystals are orthorhombic, space group Pna21; a = 16.289 (7), b = 17.991 (8), c = 17.965 (8) A?; V = 5265 (4) A?3; dcalcd = 1.084 g/mL for Z = 4; R = 5.05%. The Si-N bond distances are 1.594 and 1.626 A?, and the Si and attached N, N, and C atoms are coplanar.