1262676-16-3Relevant academic research and scientific papers
Synthesis, structure, and reactions of 1-fert-butyl-2-diphenylphosphino- imidazole
Sauerbrey, Susanne,Majhi, Paresh Kumar,Daniels, Joerg,Schnakenburg, Gregor,Bmndle, Gerhard Markus,Scherer, Katharina,Streubel, Rainer
, p. 793 - 799 (2011/04/22)
Metalation reactions were studied of a sterically demanding imidazole derivative, namely, 1-ferf-butylimidazole (1),with different metalation reagents and subsequent reaction with diphenylchlorophosphane. The reaction product, 1-ferf-butyl-2-diphenylphosphino-imidazole (2), was subjected to oxidation and complexation reactions to yield the corresponding products Ph 2(Imi)P-E (E = O (3),S (4),Se (5),W(CO)5 (8)) and in the case of borane-THF the N-BH3 coordination product 10 was obtained. The analytical data of the new compounds are discussed, including X-ray diffraction studies of 3-5.
