1262801-41-1Relevant academic research and scientific papers
A new procedure for the synthesis of α-acyloxy aldehydes from ketones via α,β-epoxy sulfides
Elberembally, Kamal
, p. 482 - 493 (2015)
α-Acyloxy aldehydes, as O-protected α-hydroxy aldehydes, have been prepared in good yields via a new procedure involving the sequence: (1) reaction of ketones with sulfur ylides to give α,β-epoxy sulfides, (2) ring opening with carboxylic acids, (3) oxida
α-Aroyloxyaldehydes: Scope and limitations as alternatives to α-haloaldehydes for NHC-catalysed redox transformations
Ling, Kenneth B.,Smith, Andrew D.
supporting information; experimental part, p. 373 - 375 (2011/02/24)
α-Aroyloxyaldehydes are readily prepared bench stable synthetic intermediates. Their ability to act as α-haloaldehyde surrogates for NHC-promoted redox esterifications and in [4+2] cycloadditions is described.
