1262843-08-2Relevant academic research and scientific papers
Chiral Bronsted acid catalyzed pinacol rearrangement
Liang, Tao,Zhang, Zhenjie,Antilla, Jon C.
supporting information; experimental part, p. 9734 - 9736 (2011/02/23)
Asymmetric pinacol rearrangement: The pinacol rearrangement has long been known to be difficult to control in terms of regioselectivity and stereoselectivity. It has been found that indolyl diols can be treated with chiral phosphoric acids to effect a regio- and enantioselective pinacol rearrangement with high efficiency (see scheme; Ar=1-naphthyl). Copyright
