1263032-17-2Relevant academic research and scientific papers
A Platinum Molecular Complex Immobilised on the Surface of Graphene as Active Catalyst in Alkyne Hydrosilylation
Mollar-Cuni, Andres,Borja, Pilar,Martin, Santiago,Guisado-Barrios, Gregorio,Mata, Jose A.
, p. 4254 - 4262 (2020)
A platinum complex bearing a N-heterocyclic carbene (NHC) ligand functionalised with a pyrene-tag is immobilised onto the surface of reduced graphene oxide (rGO). The hybrid material composed of an organometallic complex and a graphene derivative is ready
Copper-catalyzed highly regioselective silylcupration of terminal alkynes to form α-vinylsilanes
Wang, Peng,Yeo, Xue-Liang,Loh, Teck-Peng
supporting information; experimental part, p. 1254 - 1256 (2011/04/16)
A highly regioselective synthesis of branched vinylsilanes through silicon-copper additions to terminal alkynes catalyzed by copper(I) was developed using methanol as additive. The corresponding vinylsilanes were obtained with excellent branched to linear selectivity of up to 99/1 in good yields.
