1263041-93-5Relevant articles and documents
Ring-rearrangement metathesis of substituted dihydropyrans and dihydrofurans
Donnard, Morgan,Tschamber, Théophile,Le Nou?n, Didier,Desrat, Sandy,Hinsinger, Karen,Eustache, Jacques
, p. 339 - 357 (2011)
The rearrangement of dihydropyrans and dihydrofurans featuring appending olefins has been studied. The rearranged products bear resemblance with polyunsaturated di- and trisaccharides. Examples of functionalization prior to, or following, rearrangement are provided suggesting that the method should be useful for the synthesis of nonclassical saccharides. This work also illustrates the power of cascade methatetic processes for increasing molecular complexity starting from relatively simple heterocycles. Copyright