1263184-75-3Relevant academic research and scientific papers
Enantioselective synthesis of 4-hydroxy-2-cyclohexenones through a multicomponent cyclization
Barluenga, Jose,Suero, Marcos G.,De La Campa, Raquel,Florez, Josefa
supporting information; experimental part, p. 9720 - 9724 (2011/03/16)
Three metal cooperation promotes the one-pot selective coupling of a chromium carbene complex, an imide lithium enolate, and a propargylic organomagnesium reagent giving access to novel and densely functionalized 4-allenyl-2-cyclohexenones (see scheme). These useful synthetic intermediates have been prepared through a cyclization process that involves newly reported reaction steps and an unusually high level of asymmetric induction. Copyright
