1263286-86-7Relevant academic research and scientific papers
Reactivity studies of a masked three-coordinate vanadium(II) complex
Tran, Ba L.,Singhal, Madhavi,Park, Hyunsoo,Lam, Oanh P.,Pink, Maren,Krzystek,Ozarowski, Andrew,Telser, Joshua,Meyer, Karsten,Mindiola, Daniel J.
, p. 9871 - 9875 (2010)
An arene interaction can mask a low-valent and low-coordinate V II complex, [(nacnac)V(Ntol2)] (see structure), which allows for facile coordination of terminal ligands on the vanadium center. Small-molecule activation by this S=3/2 complex provides facile access to a wide range of ligand frameworks such as terminal VIV imido, V IV cyclopropene, VV nitride, and the first VV cyclo-P3 complex (see scheme). Copyright
