126330-66-3

Basic information

• Product Name: methyl 4-O-(3,4-di-O-acetyl-2,6-dideoxy-α-L-arabino-hexopyranosyl)-2,3-O-isopropylidene-α-L-rhamnopyranoside
• Synonyms: methyl 4-O-(3,4-di-O-acetyl-2,6-dideoxy-α-L-arabino-hexopyranosyl)-2,3-O-isopropylidene-α-L-rhamnopyranoside
• CAS NO: 126330-66-3
• Molecular Weight: 432.468
• Mol File: 126330-66-3.mol

Chemical Properties

• CAS DataBase Reference: methyl 4-O-(3,4-di-O-acetyl-2,6-dideoxy-α-L-arabino-hexopyranosyl)-2,3-O-isopropylidene-α-L-rhamnopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4-O-(3,4-di-O-acetyl-2,6-dideoxy-α-L-arabino-hexopyranosyl)-2,3-O-isopropylidene-α-L-rhamnopyranoside(126330-66-3)
• EPA Substance Registry System: methyl 4-O-(3,4-di-O-acetyl-2,6-dideoxy-α-L-arabino-hexopyranosyl)-2,3-O-isopropylidene-α-L-rhamnopyranoside(126330-66-3)

Safety Data

• Hazardous Substances Data: 126330-66-3(Hazardous Substances Data)

Upstream product

• 116050-47-6 Acetic acid (2S,3S,4S)-3-acetoxy-2-methyl-6-(pyridin-2-ylsulfanyl)-tetrahydro-pyran-4-yl ester 
• 14133-63-2 methyl 2,3-O-isopropylidene-α-L-rhamnoside 

Relevant articles and documents

A MILD GENERAL METHOD FOR THE SYNTHESIS OF α-2-DEOXY-DISACCHARIDES: SYNTHESIS OF L-OLEANDROSYL-L-OLEANDROSE FROM D-GLUCOSE

A mild, general method for the stereoselective synthesis of α-2-deoxy disaccharides is described using 2-deoxy-2-pyridyl 1-thioglycosides 4, 7, 8 as glycosyl donors and methyl iodide as an activator.Thus, a disaccharide 6 component of avermectin family is synthesized starting from D-glucose.

Stereoselective synthesis of α-linked 2-deoxysaccharides and furanosaccharides by the use of 2-deoxy 2-pyridyl-1-thio pyrano- and furanosides as donors and methyl iodide as an activator

A practical and highly stereoselective glycosidation methodology is described, where anomeric mixture of 2-deoxy 2-pyridyl-1-thiopyranoside donors (1-3,27) have been coupled with several sugar alcohols (4-8,29,31) on activation by methyl iodide to obtain axially linked 2-deoxysaccharides (9-17,30,32,33). Application of this method for the synthesis of disaccharide fragment 28 of avermectin is also described. Utility of this method is also shown by use of 2-pyridyl-1-thiofuranosides (34-36) as donors to prepare α-linked furanosides (42-51).