1263301-69-4Relevant academic research and scientific papers
A mild and efficient synthesis of buta-1,3-dienes substituted with a terminal pentafluoro-6-sulfanyl group
Ponomarenko, Maxim V.,Serguchev, Yurii A.,Roeschenthaler, Gerd-Volker
, p. 3906 - 3912 (2010)
An efficient four-step route towards the synthesis of conjugated 1,3-dienes substituted with a terminal SF5-group was proposed. Key steps of the synthetic sequence are the bromination of 1-(pentafluoro-λ6- sulfanyl)alk-1-enes followed by dehydrobromination of the corresponding products. Georg Thieme Verlag Stuttgart · New York.
Electron donor-acceptor (EDA)-complex enabled SF5Cl addition on alkenes and alkynes
Gilbert, Audrey,Birepinte, Mélodie,Paquin, Jean-Fran?ois
, (2021/02/03)
A new method for the addition of SF5Cl on unsaturated compounds was developed, based on the use of an electron donor-acceptor (EDA)-complex and visible light irradiation. The reaction does not require the presence of oxygen to proceed, compared
Amine-borane complex-initiated SF5Cl radical addition on alkenes and alkynes
Gilbert, Audrey,Langowski, Pauline,Delgado, Marine,Chabaud, Laurent,Pucheault, Mathieu,Paquin, Jean-Fran?ois
supporting information, p. 3069 - 3077 (2021/01/15)
The SF5Cl radical addition on unsaturated compounds was performed using an air-stable amine-borane complex as the radical initiator. This method showed to be complementary to the classic Et3B-mediated SF5Cl addition on alkenes and alkynes. A total of seven alkene and three alkyne derivatives were tested in the reaction, with yields ranging from 3% to 85%.
