126331-04-2Relevant academic research and scientific papers
PALLADIUM-CATALYZED DOUBLE CARBONYLATION OF ALKYL IODIDES BEARING PERFLUOROALKYL GROUP
Urata, Hisao,Ishii, Yoshimitsu,Fuchikami, Takamasa
, p. 4407 - 4410 (1989)
Double carbonylation of 1-perfluoroalkyl substituted 2-iodoalkanes are effectively catalyzed by palladium complexes in the presence of primary or secondary amines leading to the formation of the corresponding α-keto amides in good yields.
CARBONYLATION OF 1-PERFLUOROALKYL-SUBSTITUTED 2-IODOALKANES CATALYZED BY TRANSITION-METAL COMPLEXES
Urata, Hisao,Kosukegawa, Osamu,Ishii, Yoshimitsu,Yugary, Hideki,Fuchikami, Takamasa
, p. 4403 - 4406 (1989)
Carboxylic acids and esters with perfluoroalkyl substituent at β position were synthesized in good yields from 1-perfluoroalkyl-substituted 2-iodoalkanes and carbon monoxide with water or alcohols in the presence of base by using group VIII transition-metal complexes as catalysts.
