126336-36-5Relevant academic research and scientific papers
THIONO AND DITHIOCARBOXYLIC ESTERS WITH ADDITIONAL FUNCTIONAL GROUPS
Voss, Juergen
, p. 129 - 154 (2007/10/02)
Since powerful nucleophiles and reductants or electrophiles are required for the synthesis of thiono and dithio esters, severe difficulties arise if certain other functional groups are present in the precursor.Furthermore, strong interference may occur between a reactive substituent and the thio ester group once they are both present in a molecule. - It is, therefore, necessary - and possible - to choose thoroughly a selective method, if thiono or dithio esters with halogeno, nitro, or oxo substituents as well as bis-thiono and bis-dithio esters are to be prepared.
Facile Preparation of Monothio-orthoesters
Voss, Juergen,Wollny, Bernd
, p. 684 - 685 (2007/10/02)
O-Alkyl arenecarbothioates react with sodium alkoxide and alkyl halides to give monothio-orthoesters in good yield.
