1263390-64-2Relevant academic research and scientific papers
Microwave-assisted synthesis of a nitro-m-xylylenedioxycalix[6]arene building block functionalized at the upper rim
Galan, Hitos,De Mendoza, Javier,Prados, Pilar
, p. 7005 - 7011 (2010)
Microwave-assisted synthesis represents a new methodology to obtain calix[6]arene building blocks. The synthesis of compounds 1 and 2 is described. These compounds are A,D-m-xylylenedioxy-bridged calix[6]arenes in cone conformation, functionalized with potential amino groups in the lower rim spacer (5-position) and amino groups or their precursors in A,D-para positions at the upper rim. A conformational study has been performed for all newly synthesized compounds. New methodology involving the use ofmicrowave irradiation has allowed calix[6]arene building blocks to be obtained. The synthesis of compounds 1 and 2 is described. These compounds are A,D-m-xylylenedioxy-bridged calix[6]arenes in cone conformation, functionalized with potential amino groups in the lower rim spacer (5-position) and amino or their precursors in A,D-para positions at the upper rim. Copyright
