1263429-52-2Relevant academic research and scientific papers
Selective intramolecular C-H amination through the metalloradical activation of azides: Synthesis of 1,3-diamines under neutral and nonoxidative conditions
Lu, Hongjian,Jiang, Huiling,Wojtas, Lukasz,Zhang, X. Peter
, p. 10192 - 10196 (2010)
N2 is the only by-product in a stereospecific and highly diastereoselective intramolecular C-H amination of sulfamoyl azides with a cobalt(II)-based metalloradical catalyst (see scheme). The catalytic system has an unusual capacity for the effi
DIAMINE SYNTHESIS VIA CATALYTIC C-H AMINATION OF AZIDES
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Page/Page column 22-23, (2012/05/04)
Selective intramolecular C—H amination via metalloradical activation of azides: synthesis of 1,3-diamines under neutral and nonoxidative conditions. One aspect of the present invention is the synthesis of 1,3-diamines by intramolecular C—H amination of su
