1263429-53-3Relevant academic research and scientific papers
Catalytic Radical Process for Enantioselective Amination of C(sp3)?H Bonds
Li, Chaoqun,Lang, Kai,Lu, Hongjian,Hu, Yang,Cui, Xin,Wojtas, Lukasz,Zhang, X. Peter
supporting information, p. 16837 - 16841 (2018/11/23)
A new catalytic radical system involving CoII-based metalloradical catalysis is effective in activating sulfamoyl azides for enantioselective radical 1,6-amination of C(sp3)?H bonds, affording six-membered chiral heterocyclic sulfami
Selective intramolecular C-H amination through the metalloradical activation of azides: Synthesis of 1,3-diamines under neutral and nonoxidative conditions
Lu, Hongjian,Jiang, Huiling,Wojtas, Lukasz,Zhang, X. Peter
, p. 10192 - 10196 (2011/03/16)
N2 is the only by-product in a stereospecific and highly diastereoselective intramolecular C-H amination of sulfamoyl azides with a cobalt(II)-based metalloradical catalyst (see scheme). The catalytic system has an unusual capacity for the effi
