1263473-57-9Relevant academic research and scientific papers
New possibilities in a synthesis of (2R,4'R,8'R)-α-tocopherol (natural vitamin E)
Spivak, Anna Yu,Shafikov, Ruslan V.,Odinokov, Victor N.
, p. 67 - 75 (2011/06/21)
New methods for the synthesis of homochiral C14 and C 15-terpenoids desired as building blocks for phytilic side chain of natural α-tocopherol have been developed. A natural phytone resulted from the proposed effective method of chlo
Enantioselective transesterification of (±)-6-benzyloxy-2,5,7,8- tetramethyl-3,4-dihydro-2H-1-benzopyran-2-ylmethanol catalyzed by the Amano PS lipase in the ionic liquid [bmim]PF6
Shafikov,Spivak, A. Yu.,Odinokov
, p. 2129 - 2132 (2011/07/30)
(S)-(-)-6-Benzyloxy-2,5,7,8-tetramethyl-3,4-dihydro-2H-1-benzopyran-2- ylmethanol, a synthon for the design of natural α-tocopherol, was obtained by kinetically selective acetylation of the corresponding racemic alcohol in the presence of the Amano PS lipase from Burkholderia cepacia in the ionic liquid 1-butyl-3-methylimidazolinium hexafluorophosphate ([bmim]PF6).
