1263532-87-1Relevant articles and documents
Unusual E-selective ring-closing metathesis to form eight-membered rings
Matsui, Ryosuke,Seto, Kentaro,Fujita, Kazuhiro,Suzuki, Takahiro,Nakazaki, Atsuo,Kobayashi, Susumu
, p. 10068 - 10073 (2011/03/16)
Tied back: The title reaction was observed when a silicon-tethered diene was treated with the Hoveyda-Grubbs second-generation catalyst. The structural requirements for the E-olefin-forming ring-closing metathesis, and the transition state leading to E olefin are discussed. This methodology will be useful in the synthesis of polyketides containing a pent-2-ene-1,5-diol unit. Copyright
