1263563-57-0

Basic information

• Product Name: 2,6-bis(1-methylethyl)-N-(5,6,7-trihydroquinolin-8-ylidene)phenylamine
• Synonyms: 2,6-bis(1-methylethyl)-N-(5,6,7-trihydroquinolin-8-ylidene)phenylamine
• CAS NO: 1263563-57-0
• Molecular Weight: 306.451
• Mol File: 1263563-57-0.mol

Chemical Properties

• CAS DataBase Reference: 2,6-bis(1-methylethyl)-N-(5,6,7-trihydroquinolin-8-ylidene)phenylamine(CAS DataBase Reference)
• NIST Chemistry Reference: 2,6-bis(1-methylethyl)-N-(5,6,7-trihydroquinolin-8-ylidene)phenylamine(1263563-57-0)
• EPA Substance Registry System: 2,6-bis(1-methylethyl)-N-(5,6,7-trihydroquinolin-8-ylidene)phenylamine(1263563-57-0)

Safety Data

• Hazardous Substances Data: 1263563-57-0(Hazardous Substances Data)

Upstream product

• 56826-69-8 5,6,7,8-tetrahydro-8-quinolinone 
• 24544-04-5 2,6-diisopropylbenzenamine 

Relevant articles and documents

Efficient Catalyst for Both Suzuki and Heck Cross-Coupling Reactions: Synthesis and Catalytic Behaviour of Geometry- Constrained Iminopyridylpalladium Chlorides

A series of geometry-constrained iminopyridyl-palladium chlorides were synthesized and characterized. These phosphine-free palladium complexes were explored for their catalytic activities in both Suzuki and Heck cross-coupling reactions, achieving turnover numbers as high as 106towards various aryl bromides, even those containing various functionalities. In addition, the influence of substituents with steric and electronic factors was reflected by the differences observed in their activities. (Figure presented.).

N-(5,6,7-Trihydroquinolin-8-ylidene)arylaminonickel dichlorides as highly active single-site pro-catalysts in ethylene polymerization

A series of N-(5,6,7-trihydroquinolin-8-ylidene)arylamine ligands was synthesized and fully characterized by NMR, IR spectroscopy and elemental analysis. Dimeric N-(5,6,7-trihydroquinolin-8-ylidene)arylaminonickel dichlorides were prepared and examined by IR spectroscopy and elemental analysis, and the molecular structures of the representative nickel complexes were determined by the single crystal X-ray diffraction. On treatment with various alkylaluminiums, all the title complexes exhibited highly active, single-site active behavior for ethylene polymerization producing polyethylene (PE) waxes. The catalytic systems using the co-catalysts diethylaluminium chloride (Et2AlCl) or methylaluminoxane (MAO) were investigated in detail, and the molecular weights and distributions of the PEs obtained were found to significantly rely on the nature of the different ligands present and reaction parameters such as the molar ratios of Al/Ni, reaction temperature and reaction time. The Royal Society of Chemistry 2011.