126361-67-9Relevant academic research and scientific papers
Synthesis and Radical Induced Ring Opening Reaction of 1-Trialkylsilyl-2-vinylcyclopropanes
Miura, Katsukiyo,Oshima, Koichiro,Utimoto, Kiitiro
, p. 1665 - 1677 (2007/10/02)
A variety of trialkylsilylvinylcyclopropanes were prepared by two different routes: (a) Cyclopropanation of 1-alkenylsilanes and (b) the reactions of 1-bromocyclopropyllithium with trimethylsilyl chloride.Radical induced ring opening reaction of these cyc
STABILIZING EFFECT OF TRIALKYLSILYL GROUP ON CARBON RADICAL: RADICAL INDUCED RING OPENING OF 1-TRIALKYLSILYL-2-VINYLCYCLOPROPANES
Miura, Katsukiyo,Oshima, Koichiro,Utimoto, Kiitiro
, p. 4413 - 4416 (2007/10/02)
1-Trialkylsilyl-2-vinylcyclopropane or 3-methyl-1-trialkylsilyl-2-vinylcyclopropane provided the corresponding homoallylic silane exclusively upon treatment with PhSh, Ph3SnH, or C6F13I.On the other hand, 3-phenyl-1-trimethylsilyl-2-vinylcyclopropane or 3
