126369-97-9

Upstream product

• 603-35-0 triphenylphosphine 
• 5011-33-6 2,2-di(chloromethyl)-1-methoxypropane 

Downstream Products

• 129338-69-8 [(2-methoxymethyl-2-methyl-1,3-bis(diphenylphosphino)propane)PdCl₂] 
• 129338-65-4 (2,2-bis(diphenylphosphinomethyl)-1-methoxypropane)Mo(CO₄) 
• 129338-64-3 (2,2-bis(diphenylphosphinomethyl)-1-methoxypropane)Cr(CO)4 
• 129338-68-7 (2,2-bis(diphenylphosphinomethyl)-1-methoxypropane)nickel(II) chloride * CH₂Cl₂ 
• 474657-35-7 [(2-methoxymethyl-2-methyl-1,3-bis(diphenylphosphino)propane)Pd(acetate)2] 
• 474657-39-1 [((S)-(+)-N,N-dimethyl-α-methylbenzylamine-C,N)Pd(CH3OCH2)CCH3(CH2PPh2)2][ClO4] 

Relevant academic research and scientific papers

UNUSUAL TRIPOD-LIKE LIGANDS. SYNTHESIS OF 2,2-BIS(DIPHENYLPHOSPHINOMETHYL)-1-METHOXYPROPANE AND 2,2-BIS(PHENYLTHIOMETHYL)-1-METHOXYPROPANE

By employment of 1,1,1-tris(hydroxymethyl)ethane as the starting material, syntheses of two novel tripod-like terdentates with mixed donor properties, 2,2-Bis(diphenylphosphinomethyl)-1-methoxypropane (P2O) and 2,2-Bis(diphenylphosphinomethyl)-1-methoxypropane (S2O) are reported.Structural confirmation is based on spectroscopic and analytical results.Key words: tripodal ligands; terdentates; organophosphine ligand; organosulfur ligand.