1263961-63-2Relevant academic research and scientific papers
Metal-free activation of EH3 (E=P, As) by an ylide-like silylene and formation of a donor-stabilized arsasilene with a HS=AsH subunit
Stoelzel, Miriam,Inoue, Shigeyoshi,Meltzer, Antje,Driess, Matthias
, p. 10002 - 10005 (2010)
Twice, and faster: Reaction of the zwitterionic silylene 1 with AsH 3 occurs stepwise at ambient temperature to give the first crystalline, donor-stabilized arsasilene 3 via its 1,1-addition product (silylarsane 2). In contrast, the activation
