126402-48-0Relevant academic research and scientific papers
A NEW AMINO PROTECTING GROUP READILY REMOVABLE WITH NEAR ULTRAVIOLET LIGHT AS AN APPLICATION OF ELECTRON-TRANSFER PHOTOCHEMISTRY
Hamada, Tatsuo,Nishida, Atsushi,Yonemitsu, Osamu
, p. 4241 - 4244 (2007/10/02)
As an extension of organic photochemistry via intermolecular electron-transfer in donor-acceptor pair systems between electron-rich aromatic compounds and electron-deficient tosyl groups, we report here a new protecting group for the amino-function, 4-(4,8-dimethoxy-naphthylmethyl)benzenesulfonyl (DNMBS) group, which is readily removed, via an intramolecular electron-transfer followed by hydrolysis, with a high quantum efficiency on irradiation with light longer than 300 nm.
