126435-83-4Relevant academic research and scientific papers
Regioselective and enantiospecific rhodium-catalyzed allylic alkylation reactions using copper(I) enolates: Synthesis of (-)-sugiresinol dimethyl ether
Evans, P. Andrew,Leahy, David K.
, p. 8974 - 8975 (2007/10/03)
The transition metal-catalyzed allylic alkylation represents a fundamentally important cross-coupling reaction for the construction of ternary carbon stereogenic centers. We have developed a regioselective and enantiospecific rhodium-catalyzed allylic alk
PALLADIUM(II)-CATALYZED CLAISEN REARRANGEMENT OF 1-PHENYLETHENYL 2-PROPENYL ETHERS
Hayashi, Tamio,Yamamoto, Akihiro,Ito, Yoshihiko
, p. 2109 - 2116 (2007/10/02)
Allyl vinyl ethers containing phenyl group at α position of vinyl ether readily undergo the Claisen rearrangement in the presence of a palladium(II) catalyst to give phenyl homoallyl ketones in good yields.
The Oxidative Coupling Reaction of Allylstannanes with Trimethylsilyl Enol Ethers
Takeda, Takeshi,Ogawa, Sinji,Koyama, Masatoshi,Kato, Tetsuya,Fujiwara, Tooru
, p. 1257 - 1260 (2007/10/02)
γ,δ-Unsaturated ketones were obtained by the reaction of trimethylsilyl enol ethers with allylstannanes in the presence of tin(IV) or copper(II) salt in good yields.
