126443-50-3Relevant academic research and scientific papers
Phenylantimony(III) diorganophosphorodithioates: the crystal structure of diphenylantimony(III) di-isopropylphosphorodithioate, Ph2SbS2P(OiPr)2; unusual polymerisation through semibonding
Silvestru, Christian,Curtui, Maria,Haiduc, Ionel,Begley, Michael J.,Sowerby, D. Bryan
, p. 49 - 58 (2007/10/02)
The diphenylantimony(III) phosphorodithioates, Ph2SbS2P(OR)2 where R = Me, Et, iPr and Ph, have been prepared and the methyl and isopropyl derivatives obtained as crystalline solids.The compounds have been characterised by infrared and NMR spec
O,O-DIALKYL DITHIOPHOSPHATE COMPLEXES OF DIPHENYL ANTIMONY (III)
Karra, R.,Singh, Y. P.,Rai, A. K.
, p. 145 - 150 (2007/10/02)
Reactions of diphenylantimony chloride with the sodium salts of O,O-dialkyldithiophosphoric acids in 1:1 molar ratio in benzene solution yield neutral complexes with the general formula (RO)2PS2SbPh2 (where R = CH3, C2H5, n-C3H7, i-C3H7, n-C4H9, i-C4H9).These complexes are monomeric in nature and have been characterized by IR, 1H, 13C and 31P spectroscopy.The 31P nmr spectral data are consistent with the chelating behaviour of the dithiophosphate moieties. - Key words: O,O-dialkyldithiophosphates; Diphenyl antimony; Chelates; Monomers; Spectral Studies; Five-coordinated antimony.
