1264703-38-9Relevant academic research and scientific papers
A percyanovinylidene-ruthenium complex, Ru{=C=C5(CN) 3[=C(CN)2]2}(dppe)Cp*
Bruce, Michael I.,Morris, Jonathan C.,Nicholson, Brian K.,Skelton, Brian W.,White, Allan H.,Zaitseva, Natasha N.
, p. 653 - 656 (2011)
The reaction between Ru(C=CC=CAg)(dppe)Cp* and tcne affords a novel percyanovinylidene complex by an unusual decyano-dimerization reaction of the cyanocarbon with the diynyl fragment. This complex is also obtained from tcne and Ru{C=CC=C[Au(PPh3)]}(dppe)Cp*, together with Ru{C=CC[=C(CN)2]C[Au(PPh3)]=C(CN)2}(dppe)Cp *, formed by the anticipated [2 + 2] cycloaddition and subsequent ring-opening reactions.
