1264748-06-2

Basic information

• Product Name: 6,6'-diformyl-3,3'-bipyridine
• Synonyms: 6,6'-diformyl-3,3'-bipyridine;[3,3′-bipyridine]-6,6′-dicarbaldehyde;5,5'-diformyl-2,2'-bipyridine
• CAS NO: 1264748-06-2
• Molecular Formula: C₁₂H₈N₂O₂
• Molecular Weight: 212.20412
• Mol File: 1264748-06-2.mol

Chemical Properties

• Boiling Point: 403.0±45.0 °C(Predicted)
• Appearance: /
• Density: 1.289±0.06 g/cm3(Predicted)
• PKA: 2.27±0.12(Predicted)
• CAS DataBase Reference: 6,6'-diformyl-3,3'-bipyridine(CAS DataBase Reference)
• NIST Chemistry Reference: 6,6'-diformyl-3,3'-bipyridine(1264748-06-2)
• EPA Substance Registry System: 6,6'-diformyl-3,3'-bipyridine(1264748-06-2)

Safety Data

• Hazardous Substances Data: 1264748-06-2(Hazardous Substances Data)

Usage

Uses

Used in Coordination Chemistry:
6,6'-diformyl-3,3'-bipyridine is used as a ligand for forming complexes with metal ions, which is crucial in coordination chemistry. These metal complexes are of interest due to their potential applications in various areas.
Used in Catalysis:
In the field of catalysis, 6,6'-diformyl-3,3'-bipyridine-based metal complexes are used as catalysts to accelerate chemical reactions, offering enhanced efficiency and selectivity.
Used in Sensing Applications:
6,6'-diformyl-3,3'-bipyridine and its metal complexes are employed in sensing applications, where they can interact with specific analytes, leading to detectable changes that can be measured.
Used in Supramolecular Chemistry:
In supramolecular chemistry, 6,6'-diformyl-3,3'-bipyridine serves as a molecular building block, contributing to the self-assembly of larger, complex structures with unique properties.
Used in Organic Electronic Devices:
6,6'-diformyl-3,3'-bipyridine is used in the development of organic electronic devices such as OLEDs and OPVs, where its electronic properties are harnessed to improve device performance and efficiency.
Used in the Chemical and Materials Science Industry:
6,6'-diformyl-3,3'-bipyridine is utilized as a versatile compound across the chemical and materials science industry for its potential in creating new materials and improving existing ones through its ability to form complexes with metal ions.

Upstream product

• 85484-42-0 6,6’-dimethyl-3,3’-bipyridine 
• 1429408-42-3 6,6'-di(1,3-dioxolan-2-yl)-3,3'-bipyridine 
• 884495-16-3 5-bromo-2-(1,3-dioxolane-2-yl)pyridine 
• 223463-13-6 2-iodo-5-bromopyridine 
• 1615250-90-2 6,6'-bis(dimethoxymethyl)-3,3'-bipyridine 
• 1150632-94-2 5-bromo-2-(dimethoxymethyl)pyridine 
• 31181-90-5 5-bromo-pyridine-2-carbaldehyde 

Relevant articles and documents

Cation- and anion-exchanges induce multiple distinct rearrangements within metallosupramolecular architectures

Different anionic templates act to give rise to four distinct Cd II-based architectures: a Cd2L3 helicate, a Cd8L12 distorted cuboid, a Cd10L15 pentagonal prism, and a Cd12L18 hexagonal prism, which respond to both anionic and cationic components. Interconversions between architectures are driven by the addition of anions that bind more strongly within a given product framework. The addition of FeII prompted metal exchange and transformation to a Fe4L6 tetrahedron or a Fe10L15 pentagonal prism, depending on the anionic templates present. The equilibrium between the Cd12L18 prism and the Cd2L3 triple helicate displayed concentration dependence, with higher concentrations favoring the prism. The Cd12L18 structure serves as an intermediate en route to a hexafluoroarsenate-templated Cd10L15 complex, whereby the structural features of the hexagonal prism preorganize the system to form the structurally related pentagonal prism. In addition to the interconversion pathways investigated, we also report the single-crystal X-ray structure of bifluoride encapsulated within a Cd10L15 complex and report solution state data for J-coupling through a CH··· F- hydrogen bond indicating the strength of these interactions in solution.

Towards covalent organic frameworks with predesignable and aligned open docking sites

A strategy for the synthesis of covalent organic frameworks with open docking sites is developed. The docking sites are ordered on the channel walls and structurally predesignable for meeting various types of noncovalent interactions, thus opening a way towards designing supramolecular materials based on crystalline porous organic frameworks. This journal is the Partner Organisations 2014.

Boronate Ester-Capped Helicates

Triple-stranded helicates were obtained by metal-templated multicomponent reactions of bispyridyloxime ligands with arylboronic acids. The helicates feature two hexa-coordinated MII ions (M=Fe, Zn, or Mn), which are embedded in a macrobicyclic ligand framework, and two arylboronate ester capping groups. The latter can be used to introduce functional groups such as pyridines, aldehydes, nitriles, and carboxylic acids in apical position. The functionalized helicates have the potential to be used as nanoscale building blocks for more complex assemblies, as evidenced by the synthesis of a 3 nm-sized trianglimine.