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• 56572-25-9 2-(trifluoromethylsulfonyl)-N-tert-butoxycarbonylhydrazine 

Relevant academic research and scientific papers

Iron-Mediated Chlorotrifluoromethylation of Alkenes with Sodium Trifluoromethanesulfinate

An iron-mediated three-component chlorotrifluoromethylation of both styrenes and aliphatic alkenes has been presented here. This reaction employs ferric chloride (FeCl3) as the Cl source and the Langlois reagent (CF3SO2Na)

Anodically Coupled Electrolysis for the Heterodifunctionalization of Alkenes

The emergence of new catalytic strategies that cleverly adopt concepts and techniques frequently used in areas such as photochemistry and electrochemistry has yielded a myriad of new organic reactions that would be challenging to achieve using orthodox methods. Herein, we discuss the strategic use of anodically coupled electrolysis, an electrochemical process that combines two parallel oxidative events, as a complementary approach to existing methods for redox organic transformations. Specifically, we demonstrate anodically coupled electrolysis in the regio- and chemoselective chlorotrifluoromethylation of alkenes.

Three-Component Photoredox-Mediated Chloro-, Bromo-, or Iodotrifluoromethylation of Alkenes

A mild and simple three-component procedure for the direct vicinal halotrifluoromethylation of styrenes and aliphatic alkenes has been developed in the presence of [Ru(bpy)3](PF6)2 as a photosensitizer and Umemoto's reagen

Cu Photoredox Catalysts Supported by a 4,6-Disubstituted 2,2′-Bipyridine Ligand: Application in Chlorotrifluoromethylation of Alkenes

Interest in base metal catalysis motivates the development of Cu-based photoredox catalysts for organic synthesis. However, only a few Cu catalysts have been applied in photoredox reactions, the majority of which contain one or two 1,10-phenanthroline lig

TfNHNHBoc as a Trifluoromethylating Agent for Vicinal Difunctionalization of Terminal Alkenes

An unprecedented application of trifluoromethanesulfonyl hydrazides as trifluoromethylating agents has been demonstrated in two vicinal difunctionalization reactions of terminal alkenes: the copper-catalyzed three-component vicinal chlorotrifluoromethylat

Fluoroalkyl derivative and process for preparing the same

Fluoroalkyl derivatives which are novel compounds represented by the following general formula (I) or (II) of: STR1 or (wherein R1 stands for STR2 (where X stands for a hydrogen atom, a chlorine atom, a bromine atom, a fluorine atom, an iodine

Novel Perfluoroalkylation of Alkenes with Perfluoroalkanesulphonyl Chlorides Catalysed by a Ruthenium(II) Complex

The perfluoroalkylation of acyclic and cyclic alkenes by perfluoroalkanesulphonyl chlorides 1 has been investigated in the presence of a ruthenium(II) catalyst.The addition reactions proceeded smoothly, with extrusion of sulphur dioxide, in alkenes posses

Reaction of Trifluoromethanesulphonyl Chloride with Alkenes catalysed by a Ruthenium(II) Complex

The raction of trifluoromethanesulphonyl chloride with alkenes in the presence of dichlorotris(triphenylphosphine)ruthenium(II) gives 1:1 adducts with extrusion of sulphur dioxide.