126488-93-5Relevant articles and documents
Cu-catalyzed chlorotrifluoromethylation of alkenes with CF3SO2Cl
Zhang, Wei,Lin, Jin-Hong,Xiao, Ji-Chang
, p. 25 - 31 (2018)
Although CF3SO2Cl is an efficient chlorotrifluoromethylation reagent, an expensive transition metal complex usually has to be used. We found that CuCl2-catalyzed chlorotrifluoromethylation of alkenes with CF3SO2Cl occurred smoothly under mild conditions. A wide substrate scope and good functional group compatibility were observed.
Novel Perfluoroalkylation of Alkenes with Perfluoroalkanesulphonyl Chlorides Catalysed by a Ruthenium(II) Complex
Kamigata, Nobumasa,Fukushima, Takamasa,Terakawa, Yoshie,Yoshida, Masato,Sawada, Hideo
, p. 627 - 633 (2007/10/02)
The perfluoroalkylation of acyclic and cyclic alkenes by perfluoroalkanesulphonyl chlorides 1 has been investigated in the presence of a ruthenium(II) catalyst.The addition reactions proceeded smoothly, with extrusion of sulphur dioxide, in alkenes posses