126494-95-9Relevant academic research and scientific papers
AN EFFICIENT ROUTE TO CHIRAL t-BUTYL SULFOXIDES
Rebiere, F.,Kagan, H.B.
, p. 3659 - 3662 (1989)
The cyclic sulfite 2 of (S)-1,1-diphenyl-propane-1,2-diol 1 gave chiral sulfinates 3 or 4 with high regio- and stereoselectivities, by reaction with various organometallics.The chiral sulfinates were then transformed in almost quantitative yields into ena
A General Route to Enantiomerically Pure Sulfoxides from a Chiral Sulfite
Rebiere, F.,Samuel, O.,Ricard, L.,Kagan, H.B.
, p. 5991 - 5999 (2007/10/02)
Enantiomerically pure cyclic chiral sulfite (S)-7 (trans stereochemistry) has been easily obtained in two steps from (S)-ethyl lactate.This compound was found to react cleanly with many organometallics to give crystalline sulfinates with high regioselecti
