126503-51-3

Upstream product

• 31575-75-4 2-bromophenyl benzyl ether 
• 105938-00-9 (2S,3S,4S)-3,4-Bis-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-6-tributylstannanyl-3,4-dihydro-2H-pyran 
• 105938-00-9 1-tributylstannyl-3,4,6-tri-O-(tert-butyldimethylsilyl)-D-glucal 

Downstream Products

• 131968-55-3 (2S,3R,4R,5S,6R)-2-(2-Benzyloxy-phenyl)-3,5-bis-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-4-ol 
• 131968-58-6 (2S,3S,4R,5R,6R)-2-(2-Benzyloxy-phenyl)-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-3-ol 

Relevant academic research and scientific papers

The preparation of C-aryl glucals via palladium-catalyzed cross-coupling methods

The C-aryl glucals 17-31 have been prepared by the palladium-catalyzed cross coupling of 1-tributylstannyl-3,4,6-tri-O-(tert-butyldimethylsilyl)-b-glucal (11) and aryl bromides. The major by-product in all of these reactions is the dimer 33, the product o

The Preparation of C-Arylglycals. The Palladium-Catalyzed Coupling of 3,4,6-Tri-O-(tert-butyldimethylsilyl)-1-(tributylstannyl)-D-glucal and Aryl Bromides

The palladium-catalyzed couplings of the protected 1-(tributylstannyl)-D-glucal 1 and substituted aryl bromides provide the corresponding C-arylglucals 4-15 an a dimer 16 resulting from the homocoupling of 1.