1265215-80-2Relevant academic research and scientific papers
Facile iterative synthesis of biphenyl dendrons with a functionalized focus
Wren, Ellen J.,Wang, Xin,Farlow, Anthony,Lo, Shih-Chun,Burn, Paul L.,Meredith, Paul
, p. 4338 - 4340 (2010)
Figure Presented. An iterative procedure gives 1,3,5-phenyl-linked dendrons of up to the fourth generation and enables the formation of different generations of iridium(III) complex-cored dendrimers. The convergent synthesis uses N,N′-1,8-napthyl-3,5-dibromophenylboronamide as the key building block. The iterative synthesis cycle involves deprotection of the boronamide-focused dendron to form a boronic acid and subsequent Suzuki coupling either with the N,N′-1,8-napthyl-3,5-dibromophenylboronamide to give the next dendron generation or with an activated core to form a dendrimer.
