1265353-44-3Relevant academic research and scientific papers
Rhodium(I)-catalyzed 1,4-silicon shift of unactivated silanes from aryl to alkyl: Enantioselective synthesis of indanol derivatives
Seiser, Tobias,Cramer, Nicolai
, p. 10163 - 10167 (2010)
Let's swap! Highly reactive alkyl rhodium species undergo facile C-Si bond activation resulting in an overall 1,4-Si/Rh positional switch. This reactivity is utilized to access densely functionalized indanol derivatives in a highly enantioselective manner
