126560-07-4Relevant academic research and scientific papers
REACTION OF TRIPHENYLSTANNYL ISOCYANATE WITH 1-CHLORO-5,5-DIMETHYL-2-HEXENE
Sedel'nikova, V. N.,Terman, L. M.,Sykhranova, M. I.,Khorshev, S. Ya.
, p. 685 - 687 (2007/10/02)
The reaction of triphenylstannyl isocyanate with 1-chloro-5,5-dimethyl-2-hexene at 180 deg C takes place with substitution of the chlorine atom in the halogenoalkene by the NCO group of the isocyanate and simultaneous allylic rearrangement in the reaction complex.The reaction was used as a model to explain the deactivation of the labile chlorine atoms at the end of the growing polyene, which leads to inhibition of the thermal dehydrochlorination of polyvinyl chloride in the presence of organotin isocyanates.
